Crystalline Glaze Recipes

Crystalline glaze is a stunning technique that transforms ordinary ceramics into dazzling works of art. Known for its unique crystal patterns that form during firing, this glaze adds depth and texture that’s hard to achieve with other methods. It’s a favorite among potters looking to create one-of-a-kind pieces that catch the eye.

Mastering crystalline glaze recipes can seem daunting at first, but with the right guidance and ingredients, we can unlock its magic together. These recipes balance chemistry and creativity, allowing us to experiment and achieve beautiful results every time. Whether you’re a seasoned ceramicist or just starting out, exploring crystalline glazes opens up exciting new possibilities for your work.

Ingredients for Crystalline Glaze

To create stunning crystalline glaze effects, precise and quality ingredients are essential. Below we break down the basic components alongside the special materials that give crystal glazes their signature patterns and textures.

Basic Glaze Components

A solid foundation begins with these essential glaze materials. These ingredients form the glassy base that allows crystals to grow during firing:

  • Silica (SiO₂): The primary glass former. It creates the silica network essential for glaze solidity.
  • Feldspar: Acts as a flux, lowering the melting point to make the glaze fluid enough for crystal formation.
  • Kaolin or Ball Clay: Provides alumina, improving glaze stability and adhesion.
  • Whiting (Calcium Carbonate): Supplies calcium oxide, critical for developing crystalline structures.
  • Zinc Oxide: Enhances gloss and crystal growth by modifying melt viscosity.
  • Bentonite: Added in small amounts for suspension and glaze application properties.
Component Contribution Typical Percentage (%)
Silica (SiO₂) Glass former 45 – 55
Feldspar Flux 15 – 25
Clay (Kaolin/Bentonite) Alumina source/stability 10 – 15
Whiting (CaCO₃) Calcium oxide source 10 – 20
Zinc Oxide Gloss & crystal enhancement 2 – 5
Bentonite Suspension aid 1 – 3

Special Materials for Crystalline Effects

What sets crystalline glazes apart are the special ingredients that encourage controlled crystal growth during cooling:

  • Zinc Oxide (ZnO): Used in higher amounts than in standard glazes to promote large crystal development.
  • Magnesium Carbonate or Dolomite: Introduce magnesium oxide and calcium oxide which are crucial for crystal nucleation and growth.
  • Barium Carbonate: Sometimes added to improve the size and clarity of crystals.
  • Titanium Dioxide (TiO₂): Acts as a nucleating agent, triggering crystal formation.
  • Strontium Carbonate: Enhances crystal size and adds unique hues.

These materials work together by altering the glaze viscosity and encouraging crystals to form throughout the melt as it slowly cools. Precise balance ensures beautiful, controlled crystalline patterns rather than a muddy or overly fluid surface.

Special Ingredient Role Typical Range (%)
Zinc Oxide Promotes large crystal growth 8 – 15
Magnesium Carbonate Calcium and magnesium source for crystallization 3 – 8
Barium Carbonate Enhances crystal clarity and size 1 – 5
Titanium Dioxide Nucleation agent for crystal formation 2 – 6
Strontium Carbonate Modifies crystal color and size 1 – 4

We carefully combine these basic and special materials according to desired effects and firing schedules, ensuring our crystalline glaze recipes consistently yield stunning and unique ceramic surfaces.

Equipment and Tools Needed

To create flawless crystalline glaze effects, having the right equipment and tools is essential. These ensure precise control over the firing process and accurate glaze application, which are critical for beautiful crystal development.

Kiln Requirements

For crystalline glaze firing, a kiln capable of reaching and maintaining high temperatures with fine control is a must. Here are the key kiln attributes:

  • Temperature Range: The kiln must reliably reach 2320°F (1270°C) or higher, essential for melting the glaze and allowing crystals to form.
  • Soak Capability: A programmable soak phase at peak temperature for 1-2 hours supports crystal nucleation and growth.
  • Ramp Control: Precise ramp-up and ramp-down control, especially during the cooling cycle, to create the optimal cooling rate for crystal formation.
  • Ventilation: Proper kiln ventilation to avoid unwanted oxidation or reduction that could affect glaze appearance.
  • Size & Shelving: Adequate interior space and kiln shelves that can withstand high temps without warping to safely hold your ceramic pieces.
Feature Specification Importance
Max Temperature ≥ 2320°F (1270°C) Critical for glaze melt and crystal formation
Soak Time 1-2 hours Enables crystal growth
Ramp Control Programmable, gradual cooling Controls crystal size and pattern
Ventilation Adjustable Ensures glaze color stability
Kiln Size & Shelves Large enough for pieces with heat-resistant shelves Safety and ease of firing

Glaze Application Tools

Accurate and consistent glaze application directly affects the final appearance of the crystals. We recommend using:

  • Spray Gun or Airbrush: For even glaze coats, minimizing brush marks and ensuring uniform thickness crucial for crystal growth.
  • Soft Brushes: Ideal for touch-ups or applying glaze to detailed areas without disturbing underlying layers.
  • Glove and Mask: For safely handling glaze powders and spray fumes.
  • Mixing Buckets and Stirrers: To blend glaze suspensions thoroughly, keeping particles evenly suspended for consistent application.
  • Scale: Precision weighing of raw materials for glaze recipes, ensuring repeatable and balanced glaze results.
  • Sponges & Towels: To clean spills and wipe excess glaze cleanly before firing.

By equipping ourselves with these tools and a high-quality kiln, we set the foundation for successful and stunning crystalline glaze results that showcase vivid, intricate crystal formations.

Preparing the Clay Body

Before achieving the mesmerizing crystalline glaze effects, it’s vital to focus on Preparing the Clay Body properly. This ensures optimal adhesion of the glaze and supports the growth of crystals during firing.

Choosing the Right Clay

Selecting the right clay body is key to successful crystalline glaze development. We recommend using a white or light-colored stoneware or porcelain clay because darker clays can interfere with the crystal visibility and alter the glaze color.

Clay Type Characteristics Suitability for Crystalline Glaze
Porcelain Fine, smooth, high firing temperature Excellent for crisp crystal definition
White Stoneware Slightly coarser, durable Very good for crystalline patterns
Red or Dark Clay Iron-rich, lower firing range Generally avoided due to color interference

We also consider clay maturity temperature; it should be compatible with glaze firing, typically between 2300°F and 2350°F (1260°C to 1287°C). A clay that is too porous or fires at too low a temperature may cause defects or weaken the glaze surface.

Pre-Firing Preparation

Proper Pre-Firing Preparation of the clay body ensures a smooth surface and strong glaze adherence:

  1. Bisque Fire the Clay – Fire the ware to a bisque temperature of around 1850°F (1010°C). This removes moisture while maintaining porosity for better glaze absorption.
  2. Surface Cleaning – Thoroughly clean the bisque ware using a soft brush or damp sponge to remove dust and debris that can disrupt glaze application.
  3. Test Fit and Smoothness – Ensure your clay body surface is free from cracks and imperfections by lightly sanding rough patches with fine-grit sandpaper. A smooth surface encourages uniform glaze layering.
  4. Apply a Glaze Binder (Optional) – For highly reactive crystal recipes, some potters apply a light coat of glaze binder to improve the glaze grip on the clay body.

Crystalline glaze thrives when the clay body creates a supportive, stable base. Preparing our clay meticulously allows the crystal formations to flourish beautifully during firing.

With a well-chosen clay and mindful pre-firing preparation, we lay the groundwork for stunning crystalline glaze results that showcase intricate crystal growth and vibrant finishes.

Mixing the Crystalline Glaze

Mixing the crystalline glaze requires precision and care to ensure the perfect balance of ingredients that promotes crystal growth and glaze stability. Let’s walk through the essential steps to measure and combine the materials effectively.

Measuring and Combining Ingredients

Accurate measurement is critical for successful crystalline glaze recipes. We recommend using a digital scale with a precision of at least 0.1 grams to weigh each component. Follow the sequence below to combine your ingredients for uniform blending:

  • Begin with the dry ingredients: silica, feldspar, kaolin (or ball clay), and whiting.
  • Weigh each material precisely according to your recipe formula.
  • Add special materials like zinc oxide, magnesium carbonate, barium carbonate, titanium dioxide, and strontium carbonate last for accurate control.
  • Place all dry ingredients into a clean mixing container.
  • Thoroughly mix the powders using a sieve or by hand until the blend is consistent.
  • Slowly add water in small increments while stirring to form a smooth slurry or slip.
  • Aim for a glaze viscosity similar to a heavy cream for optimal application.
Ingredient Typical Percentage Range (%) Purpose
Silica 20 – 30 Glass former
Feldspar 25 – 40 Flux
Kaolin/Ball Clay 5 – 15 Suspension aid
Whiting 15 – 25 Flux and hardness
Zinc Oxide 5 – 10 Crystal promoter
Magnesium Carbonate 1 – 5 Crystal growth modifier
Barium Carbonate 0.5 – 2 Crystal structure enhancer
Titanium Dioxide 1 – 3 Opacifier, crystal influence
Strontium Carbonate 0.5 – 2 Crystal size and shape control

Tips for Consistency

To maintain consistent crystalline glaze results, observe the following best practices:

  • Always mix fresh batches with measured ingredients. Avoid estimating.
  • Use distilled or filtered water for purity and control in slurry consistency.
  • Let the glaze slurry rest for at least 12 hours to fully hydrate and de-air.
  • Re-stir gently but thoroughly before application to prevent settling.
  • Check the glaze thickness using a viscosity cup aiming for 40–50 seconds flow time (Zahn #4 cup standard).
  • Test small samples with your kiln schedule before applying to larger pieces.
  • Document every batch’s formula, mixing ratios, and firing outcomes for refinement.

By carefully measuring and blending our crystalline glaze, we set the foundation for stunning crystal formations that captivate and elevate our ceramic art.

Applying the Crystalline Glaze

Achieving the perfect crystalline glaze finish demands careful attention during the application process. Precise surface preparation and expert Application Techniques ensure vivid crystal formations and flawless coverage.

Surface Preparation

Before applying the glaze, we must prepare the ceramic surface meticulously to maximize adhesion and crystal growth. Follow these steps:

  • Clean the bisque-fired piece thoroughly to remove dust, oils, or residues. Use a damp sponge or soft brush.
  • Smooth the surface by lightly sanding any rough areas; crystals develop best on even surfaces.
  • Choose a white or light-colored stoneware or porcelain clay body to enhance crystal visibility.
  • Optionally, apply a thin coat of glaze binder to improve glaze adherence, especially on porous or uneven surfaces.
  • Avoid fingerprints or contaminants by wearing gloves during handling.

Proper surface preparation creates an optimal canvas for the glaze to interact evenly and supports consistent and beautiful crystal growth.

Application Techniques

The technique applied directly affects the glaze’s visual impact and texture. We recommend these proven methods:

Technique Description Best For
Dipping Submerge the piece in the glaze for an even coat Uniform coverage on larger items
Brushing Use soft brushes to apply thin, controlled layers Small details and edges
Spraying Use spray guns or airbrushes for fine mist coverage Smooth finish with minimal texture
Pouring Pour glaze over the piece to create flowing effects Experimental textures

Key tips:

  • Apply multiple thin layers rather than a single thick coat to avoid glaze running or uneven crystal development.
  • Allow each layer to dry thoroughly before applying the next.
  • Maintain a consistent glaze thickness of about 0.5 to 1 mm for optimal crystal formation.
  • Document each application method and thickness as these variables influence final crystal size and distribution.

As one ceramic artist noted, “The glaze’s beauty lies in the balance—too thick or thin, and the crystals either won’t form or will become distorted.”

By combining precise surface prep with controlled application techniques, we set the foundation for stunning crystalline glaze results that highlight unique, vibrant crystal patterns.

Firing Process

The Firing Process is the cornerstone of achieving extraordinary crystalline glaze effects. Precise control over temperature and timing during firing unlocks the growth of beautiful, intricate crystals on our ceramic pieces.

Firing Schedule for Crystalline Glazes

To develop sharp and distinct crystals, the firing schedule must follow a deliberate sequence of controlled heating, soaking, and cooling stages. This ensures the glaze reaches maturity and creates optimal conditions for crystal formation.

Stage Temperature (°F / °C) Duration Notes
Initial Ramp 2300°F / 1260°C 2-3 hours Slow rise to avoid thermal shock
Soak for Maturity 2300-2350°F / 1260-1287°C 1-2 hours Allows glaze to melt and crystals to nucleate
Controlled Cooling 1850°F / 1010°C Variable Critical phase for crystal growth; controlled ramp down
  • We recommend ramping slowly between 1850°F (1010°C) and 2300°F (1260°C) to promote gradual crystal development.
  • Prolonged soak times at peak temperature improve crystal size and clarity.
  • Accurate temperature holding at the peak is essential—our kiln must maintain stability within ±10°F (±5.5°C).

Cooling and Crystallization Stage

The most crucial phase in crystalline glaze firing is the controlled cooling or crystallization stage. This slow cooling interval allows the zinc oxide, titanium dioxide, and other special materials to form visible crystals as the glaze solidifies.

“Crystal growth is highly dependent on the slow reduction of temperature and carefully timed holds during the cooling cycle.”

Key cooling guidelines include:

  • Slow Cooling Rate: Reduce kiln temperature gradually at about 100°F (55°C) per hour from the peak temperature down to 1850°F (1010°C).
  • Hold/Soak at Crystallization Temperature: Maintain the kiln at around 1850°F (1010°C) for 1-3 hours to encourage extensive crystal development.
  • Final Cool: After the soak hold, allow the kiln to cool naturally to room temperature without rapid drops.

This phase defines the size, shape, and distribution of crystals appearing on the surface. Non-uniform cooling can cause inconsistent patterns and crack formations.

By mastering this firing and cooling cycle, we can unlock the full visual potential of our crystalline glaze recipes, revealing vibrant, dimensional crystal clusters that captivate and inspire.

Troubleshooting Common Issues

Even with careful preparation, crystalline glaze recipes can present challenges during firing. Here, we tackle common problems and provide clear solutions to help us achieve those stunning crystal effects every time.

Crystals Not Forming

If our glaze lacks visible crystal growth, the cause usually relates to firing schedule, glaze composition, or application technique. Let’s explore the potential causes and corrective steps:

Issue Cause Solution
No crystals after firing Peak temperature too low Increase kiln temperature to recommended range (2300°F+)
Soak time too short Extend soak at peak to allow crystal development
Rapid cooling Implement slow cooling phase, especially between 1800°F and 1400°F
Incorrect glaze chemistry Adjust zinc oxide, barium carbonate, or titanium dioxide percentages
Thin glaze layers Apply multiple thin layers for sufficient glaze thickness

“Crystal growth thrives within a precise temperature window and slow cooling phase.”

Key reminders:

  • Maintain soak times typically between 10 and 30 minutes at peak temperature.
  • Slow cooling rates around 50°F per hour encourage dendritic crystal patterns.
  • Ensure even, consistent glaze thickness to provide a uniform surface for crystals.

Glaze Defects and Solutions

Various glaze defects can affect our crystalline glaze finish. Identifying these defects early helps us fine-tune our recipe or firing process.

Defect Description Likely Cause Recommended Fix
Crazing Network of fine cracks Mismatch between glaze and clay thermal expansion Adjust silica / feldspar ratios to balance fit
Pinholing Tiny holes on glaze surface Air trapped during application or firing Improve glaze suspension; slower drying or firing
Crawling Glaze peels or pulls away from substrate Dirty or greasy bisque surface; too thick glaze Clean better; apply thinner glaze layers
Blistering Raised bubbles or blisters Overfiring or rapid temperature increase Slow ramp up; lower peak temperature
Matte or dull finish Lack of crystal gloss or shine Insufficient zinc or flux in glaze Boost fluxes like zinc oxide for luster

“Attention to both chemistry and kiln atmosphere ensures our glaze’s crystalline beauty shines.”

General tips for defect troubleshooting:

  • Always clean bisqueware thoroughly before glaze application.
  • Control glaze application for even coverage avoiding excessive thickness.
  • Record firing schedules and results to track what changes yield improvements.

By meticulously diagnosing issues and refining our crystalline glaze recipes and firing techniques, we bring our ceramic works closer to the cherished goal of vibrant, intricate crystal formations.

Variations of Crystalline Glaze Recipes

Exploring different variations of crystalline glaze recipes allows us to customize the visual impact and tactile quality of our ceramic pieces. By adjusting colorants, firing schedules, and ingredient proportions, we can create dazzling effects personalized to our artistic vision.

Color Variations

Color plays a crucial role in defining the mood and style of crystalline glaze finishes. By incorporating various metal oxides or stains into the base recipe, we can achieve a wide spectrum of hues that enhance and highlight the unique crystal formations.

  • Cobalt Oxide (0.5%–2%)

Produces deep blues that contrast beautifully with lighter crystals.

  • Iron Oxide (1%–4%)

Creates warm browns and rust tones, adding earthy richness.

  • Copper Carbonate (1%–3%)

Offers vibrant greens to teals, depending on firing atmosphere.

  • Manganese Dioxide (0.5%–2%)

Yields purple and violet shades, producing dramatic effects.

While these metal oxides enrich color, it’s essential to balance their quantities to avoid suppressing crystal growth or causing unwanted surface defects.

Colorant Typical Usage Percentage Resulting Color
Cobalt Oxide 0.5% – 2% Deep Blue
Iron Oxide 1% – 4% Warm Brown / Rust
Copper Carbonate 1% – 3% Green to Teal
Manganese Dioxide 0.5% – 2% Purple / Violet

“The subtle interplay between colorants and crystal clarity defines the allure of crystalline glaze finishes.”

Texture and Size of Crystals

Controlling the texture and size of crystals is fundamental in developing the signature appearance of crystalline glazes. We influence these aspects mainly through ingredient ratios and firing profiles.

  • Zinc Oxide Concentration

Increasing zinc oxide encourages larger crystal growth but can reduce overall glaze transparency.

  • Barium Carbonate Addition

Supports smooth crystal edges and finer crystal dispersal.

  • Extended Soak Time at Peak Temperature

Promotes larger and more defined colonies of crystals.

  • Cooling Rate Control

Slower cooling encourages fewer but larger crystals, while faster cooling yields many smaller crystals.

Factor Effect on Crystals
Higher Zinc Oxide (%) Larger crystals, less transparency
Barium Carbonate Presence Smoother edges, finer crystal patterns
Extended Soak (1-2 hours) Larger crystal clusters
Cooling Speed – Slow Fewer, larger crystals
Cooling Speed – Fast More numerous, smaller crystals

“The marriage of chemistry and kiln control lets us tailor crystal size and texture, shaping the distinctive beauty of each piece.”

By experimenting within these parameters, we can create crystalline glaze variations ranging from delicate frost-like veils to bold, jewel-like crystal bursts.

Safety Tips When Working With Crystalline Glazes

Working with crystalline glaze recipes requires more than just precision and artistry—it demands strict adherence to safety protocols to protect ourselves and our surroundings. Below are essential safety tips to keep in mind as we mix, apply, and fire these specialized glazes.

1. Use Proper Personal Protective Equipment (PPE)

Handling dry glaze materials and firing kilns exposes us to dust and high temperatures. Always wear:

  • Dust masks or respirators rated for fine particulate matter to avoid inhalation of glaze powders that often contain heavy metals and silica.
  • Safety goggles to shield our eyes from splashes or dust during mixing and application.
  • Gloves, preferably nitrile or latex, to prevent skin contact with potentially toxic materials.
  • Protective clothing such as long sleeves and aprons to minimize skin exposure.

“Protecting our respiratory system and skin is non-negotiable when working with crystalline glazes, as many ingredients pose health risks upon prolonged exposure.”

2. Ensure Adequate Ventilation

The workspace must have:

  • Good airflow during mixing to disperse glaze dust.
  • Fume extraction systems or open windows when firing kilns to remove gases and fumes that may be released at high temperatures.

3. Handle Raw Materials Carefully

Ingredients like zinc oxide, barium carbonate, and strontium carbonate are common in crystalline glazes but are toxic if mishandled. Follow these guidelines:

  • Store materials in clearly labeled airtight containers.
  • Avoid cross-contamination between batches by cleaning tools and surfaces thoroughly.
  • Never eat, drink, or smoke while handling powders.

4. Safe Kiln Operation

Operating a kiln at temperatures upwards of 2300°F (1260°C) involves risks. Observe these safety measures:

  • Maintain clear working areas free of flammable materials near the kiln.
  • Use kiln gloves and proper tools to load and unload pieces.
  • Monitor kiln temperature carefully using calibrated controllers.
  • Allow the kiln to cool completely before opening.
Safety Equipment Purpose Key Tips
Dust Mask/Respirator Prevent inhalation of hazardous dust Use N95 or better rating
Safety Goggles Protect eyes from dust and splashes Ensure a snug fit
Gloves (Nitrile/Latex) Protect skin from chemicals Change regularly to avoid contamination
Protective Clothing Minimize skin exposure Wear long sleeves, aprons
Ventilation/Fume Extraction Remove harmful airborne particles and gases Use fans or exhausts during mixing/firing

5. Emergency Preparedness

Have these ready and accessible in your workspace:

  • First aid kit for minor injuries.
  • Eye wash station in case of accidental splashes.
  • Fire extinguisher rated for electrical and chemical fires near the kiln area.

6. Proper Waste Disposal

Dispose of leftover glaze materials and contaminated water responsibly:

  • Do not pour glaze slurry or wash water directly down drains.
  • Follow local hazardous waste regulations for disposal.

“Respecting safety guidelines ensures a healthy environment and the longevity of our creative work in crystalline glazing.”

By integrating these safety practices into our workflow, we safeguard ourselves while continuing to explore the stunning possibilities of crystalline glaze recipes with confidence and care.

Conclusion

Exploring crystalline glaze recipes opens up a world of creative possibilities for our ceramic work. With patience and attention to detail, we can master the delicate balance of ingredients and firing techniques that bring these stunning crystal patterns to life.

By embracing experimentation and refining our process, each piece becomes a unique expression of artistry and skill. The journey may be challenging, but the dazzling results make it well worth the effort. Let’s continue pushing the boundaries of our craft with confidence and curiosity.

Frequently Asked Questions

What is crystalline glaze in ceramics?

Crystalline glaze is a technique where unique crystal patterns form on ceramics during firing, enhancing visual depth and texture. It requires precise ingredient blends and firing schedules to create striking, intricate crystal formations on pottery surfaces.

Can beginners successfully use crystalline glaze?

Yes, beginners can achieve beautiful crystalline glaze effects with proper guidance, quality materials, and patience. Mastery comes with practice, but following detailed recipes and firing schedules helps produce stunning results even for less experienced potters.

What are the essential ingredients for crystalline glaze?

Basic ingredients include silica, feldspar, kaolin or ball clay, whiting, zinc oxide, and bentonite. Special materials like zinc oxide, magnesium carbonate, barium carbonate, titanium dioxide, and strontium carbonate enhance crystal growth and glaze appearance.

What kiln features are needed for crystalline glazing?

A kiln should reach at least 2320°F (1270°C), maintain soak times for crystal growth, have precise ramp and cooling control, ensure good ventilation, and provide adequate space and shelving for firing crystalline glaze pieces.

How should the clay body be prepared for crystalline glaze?

Use a white or light-colored stoneware or porcelain clay compatible with glaze firing temperatures (about 2300°F – 2350°F). Bisque fire first, clean and smooth the surface, and optionally apply a glaze binder to improve adhesion and crystal growth.

How is crystalline glaze mixed?

Weigh ingredients accurately using a digital scale. Combine dry materials in a specific order, add distilled water, mix thoroughly, let the glaze rest, and document each batch. Precise measurement and consistency are key for desired crystal effects.

What are the best glaze application techniques?

Options include dipping, brushing, spraying, or pouring. Apply multiple thin, even layers after proper surface prep (cleaning, smoothing, optional binder) to promote vivid and well-defined crystal formations on the ceramic piece.

How does the firing process affect crystalline glaze?

Controlled heating, soaking at peak temperature, and slow cooling are essential. Soaking promotes crystal growth while the cooling rate influences crystal size and shape. Following exact firing schedules unlocks the glaze’s full visual potential.

What common problems occur when firing crystalline glazes?

Issues include no crystal formation (often due to low temperature or soak time), crazing, pinholing, and blistering. Correct by adjusting kiln temperature, soak duration, and glaze recipe to improve crystal development and surface finish.

How can crystalline glaze colors and textures be varied?

Adjust colorants like cobalt oxide (blue), iron oxide (brown), copper carbonate (green), and manganese dioxide (purple). Modify ingredients and firing profiles to control crystal size and texture, creating effects from delicate frost-like to bold jewel-like appearances.

What safety precautions should be taken when working with crystalline glazes?

Wear PPE such as dust masks, goggles, gloves, and protective clothing. Ensure proper ventilation when mixing and firing, handle materials carefully, maintain clean workspaces, and follow safe kiln operation and waste disposal procedures to protect health and environment.

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